منابع مشابه
Reverse Differential Pulse Voltammetry and Polarography
In this paper we obtain the analytical solution for the reverse Werential pulse O P ) technique for a slow electronic transfer process, starting fkom expressions obtained previously for the faradaic response to a triple potential pulse. The solutions are valid for the planar approximations of a static mercury drop electrode and of a dropping mercury electrode. An irreversible reduction process ...
متن کاملTrace Determination of Azathioprine by Differential Pulse Polarography
A simple and rapid differential pulse polarographic method was developed for the trace determination of azathioprine. A welldefined polarogram with three peaks was obtained in acetate buffer (pH 5.0) with peak potentials -0.27 V, -0.73 V and -1.02 V. The current-concentration linearity was found extend up to 5 x 10 mol L (r = 0.9992) with minimum detection limit of 2.8x10 mol L. The values of r...
متن کاملIndirect determination of thallium by differential-pulse polarography.
The method is based on the separation of Tl(I) as Tl(2)HPMo(12)O(40), stripping of the molybdate, and measurement of the peak current in differential-pulse polarography of the molybdenum. The calibration graph is linear over the range 2-12 ppm of thallium. The relative standard deviation is 1.2% (7 replicates each containing 500 microg of thallium). The current due to reduction of the molybdenu...
متن کاملEstimation of Tegaserod Maleate by Differential Pulse Polarography
A highly sensitive differential pulse polarographic method has been developed for the estimation of tegaserod maleate after treating it with hydrogen peroxide solution. The oxidation of tegaserod maleate is a reversible process as the oxidized product could be reduced at hanging mercury drop electrode in a quantitative manner using differential pulse polarography mode. The limit of quantificati...
متن کاملElectrochemical investigation of hapten-antibody interactions by differential pulse polarography.
The binding of electroactively labeled estriol with estrogen-specific antibody and its subsequent displacement by unlabeled estriol have been monitored by differential pulse polarography. Estriol was found to be electro-inactive in the potential range -200 mV to -1000 mV vs a silver/silver chloride electrode. Estriol labeled in the 2 and 4 position with nitro groups was electroactive, giving tw...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Study of Polarography
سال: 1954
ISSN: 1884-7684
DOI: 10.5189/revpolarography1953.2.63